Journal
JOURNAL OF INDUSTRIAL AND ENGINEERING CHEMISTRY
Volume 19, Issue 6, Pages 1981-1989Publisher
ELSEVIER SCIENCE INC
DOI: 10.1016/j.jiec.2013.03.007
Keywords
Linear alkylbenzene; RSM; ANN; Preyssler heteropoly acid; Silica-supported catalyst
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Design of experiments (DOE) and artificial neural networks (ANNs) were successfully applied for studying the operating parameters of benzene alkylation with 1-decene over H-14[NaP5W30O110]/SiO2 catalyst. In this reaction catalyst loading, catalyst weight percent and benzene to 1-decene molar ratio (Bz/C,(10)) were chosen as independent variables in experimental design. Prediction of 1-decene conversion and 2-phenyldecane selectivity was performed applying response surface method (RSM) and ANN models. Final selected multi-layer (3-6-2-2) ANN model resulted a coefficient of determination (R-2) of 0.95 for 1-decene conversion and 0.99 for 2-phenyldecane selectivity, while the R-2 of RSM was 0.93 and 0.92 for these two parameters. (C) 2013 The Korean Society of Industrial and Engineering Chemistry. Published by Elsevier B.V. All rights reserved.
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