Journal
JOURNAL OF INDUSTRIAL AND ENGINEERING CHEMISTRY
Volume 14, Issue 3, Pages 297-302Publisher
ELSEVIER SCIENCE INC
DOI: 10.1016/j.jiec.2008.01.001
Keywords
titanium nitride; inductively coupled plasma reactive ion etching; Cl-2/Ar plasma
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An inductively coupled plasma reactive ion etching of TiN thin films was carried out using a Cl-2/Ar gas chemistry. The etch characteristics such as the etch rate and etch profile were investigated by varying gas concentration and etch parameters including coil radio frequency (rf) power, dc-bias voltage and gas pressure. As the Cl-2 concentration increased, the etch rates of TiN thin films increased while the sidewall slopes of the etched films became slanted without the redeposition or etch residues. With increasing coil rf power and dc-bias voltage, the etch rates increased and etch slope became steep. Gas pressure has a little effect on etch rate and better etch profile was obtained at low gas pressure. Finally, highly anisotropic etching of TiN thin a film using a photoresist mask was achieved at the optimized etch condition. (C) 2008 Published by Elsevier B.V. on behalf of The Korean Society of Industrial and Engineering Chemistry.
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