Journal
JOURNAL OF INCLUSION PHENOMENA AND MACROCYCLIC CHEMISTRY
Volume 68, Issue 1-2, Pages 207-217Publisher
SPRINGER
DOI: 10.1007/s10847-010-9769-5
Keywords
Calixarene; Amphiphilic; Structure; Langmuir; Synthesis
Categories
Funding
- Polish Ministry of Science and Higher Education [401/ERA-NET/2009]
- DGA
- CNRS
Ask authors/readers for more resources
The para-acylcalix[6]arenes bearing butanoyl, hexanoyl and octanoyl chains have been synthesized by Friedel-Crafts acylation of the parent calixarene. Persubstitution at the phenolic face was achieved to yield the methoxy-diethoxy, ethoxycarbonylmethoxy, methoxycarboxylic acid and butoxysulphonate derivatives. In the case of the derivatives, 5,11,17,23,29,35-hexa-octanoyl-37,38,39,40,41,42-hexa-methoxy-diethoxy-calix[6]arene, 5,11,17,23,29,35-hexa-butanoyl-37,38,39,40,41,42-hexaethoxycarbonyl methoxy-calix[6]arene and 5,11,17,23,29,35-hexa-octanoyl-37,38,39,40,41,42-hexaethoxycarbonyl methoxy-calix[6]arene the solid state structures were determined and show inclusion of two ester groups in the cavity. While for the para-acylcalix[6]arenes no stable monolayers can be formed at the air-water interface, stable monolayers are formed with the methoxy-diethoxy, ethoxycarbonylmethoxy, methoxycarboxylato compounds which show apparent molecular areas in the range 150-200 (2) depending on the length of the acyl chains.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available