Journal
JOURNAL OF INCLUSION PHENOMENA AND MACROCYCLIC CHEMISTRY
Volume 64, Issue 1-2, Pages 83-94Publisher
SPRINGER
DOI: 10.1007/s10847-009-9539-4
Keywords
Carboxyester modified gamma-cyclodextrin; Fullerene C-60; Inclusion complexes; Shear induced release from microgel
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Funding
- Egide ECO-NET program (France) [N 12556 WC]
- Russian Foundation for Basic Research [07-03-91681-PA_a]
- Romanian Academy [03/2008]
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Carboxyl modified gamma-cyclodextrin (CDSA) with a substitution degree of about 9.5 was prepared by the esterification of gamma-cyclodextrin (CD) with succinic anhydride in pyridine at 90 A degrees C. The chemical composition and the structure of CDSA were characterized by FT-IR, MALDI-TOF, X-ray diffraction pattern, potentiometric titration and TGA. Modified and native gamma-cyclodextrin associate with fullerene (C-60) in DMF-toluene mixture resulting 1:1 CDSA:C-60 and CD:C-60 inclusion complexes. Aqueous solutions of native cyclodextrin, carboxyl-modified cyclodextrin and their inclusion complexes with C-60 were used as microgel solvent (or swelling agent) for controlled release application. The release of solutions was induced by shear stress and demonstrated using rheo-optical set-up.
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