Journal
ORGANOMETALLICS
Volume 34, Issue 11, Pages 2515-2521Publisher
AMER CHEMICAL SOC
DOI: 10.1021/om501223a
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Funding
- EPSRC [EP/E-32575/1]
- EPSRC [EP/J003921/1] Funding Source: UKRI
- Engineering and Physical Sciences Research Council [EP/J003921/1] Funding Source: researchfish
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The synthesis, structure, and spectroscopic details of a series of beta-diketiminato lead(II) alkyl complexes are described. The Hammett correlation between the Pb-207 NMR. chemical shifts sigma(para). Hammett constant was examined computationally and found to be due to the paramagnetic shielding contribution, whereas the diamagnetic and spin-orbit coupling contributions remained fairly constant across this series of compounds.
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