Journal
ORGANOMETALLICS
Volume 35, Issue 1, Pages 27-31Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.organomet.5b00846
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Funding
- University of East Anglia
- Johnson Matthey plc.
- ERC [338944 - GOCAT]
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The Au(II) (CNC)-N-boolean AND-C-boolean AND pincer complex [((CNC)-N-boolean AND-C-boolean AND)Au](2) is stable under thermal conditions but disproportionates on irradiation in solution to give an Au(I)(4)Au(III)(4) mixed-valence aggregate with a 20-membered macrocyclic structure, consisting of four linear Au(I) C-Au-N building blocks, each of which is decorated with a square planar ((CNC)-N-boolean AND-C-boolean AND)Au(III) substituent. In the crystal, the rings are stacked to form solvent-filled channels with an internal diameter of 8.3 angstrom and a cross-channel Au-I center dot center dot center dot Au-I distance of 7.7 angstrom.
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