Journal
ORGANOMETALLICS
Volume 34, Issue 17, Pages 4205-4208Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.organomet.5b00668
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- Deutsche Forschungsgemeinschaft
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A 1,3,4-trisubstituted borole is readily obtained by a 1,1-carboboration sequence starting from a bis(ethynyl)-borane and B(C6F5)(3). Subsequent photolysis converts it to the 1,2,5-trisubstituted borole by means of a di-pi-borane rearrangement.
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