4.8 Article

Visible-Light-Driven Photocatalytic Initiation of Radical Thiol-Ene Reactions Using Bismuth Oxide

Journal

ORGANIC LETTERS
Volume 17, Issue 23, Pages 5756-5759

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.5b03184

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A nontoxic and inexpensive photocatalytic initiation of anti-Markovnikov hydrothiolation of olefins using visible light is reported. This method is characterized by low catalyst loading, thereby enabling a mild and selective method for radical initiation in thiol-ene reactions between a wide scope of olefins and thiols.

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