4.8 Article

A Free Radical Cascade Silylarylation of Activated Alkenes: Highly Selective Activation of the Si-H/C-H Bonds

Journal

ORGANIC LETTERS
Volume 17, Issue 10, Pages 2534-2537

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.5b01067

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Funding

  1. National Science Foundation of China [21272096, 21472080]

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The first example of silylarylation of activated alkenes with silanes is reported via selective activation of the Si-H/C-H bonds, which allows efficient access to silylated oxindoles through a free-radical cascade process.

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