Journal
ORGANIC LETTERS
Volume 17, Issue 5, Pages 1256-1259Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.5b00241
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Funding
- St. Olaf College, National Institutes of Health [R15 GM107892]
- American Chemical Society [52224-UNI3]
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A Ni-catalyzed method for the coupling of perfluorobenzoates with aryl halides and pseudohalides is described. Aryl iodides, bromides, chlorides, triflates, and tosylates participate in these transformations to afford the products in good yields. Penta-, tetra-, and trifluorinated biaryl compounds are obtained using these newly developed Ni-catalyzed decarboxylative cross-coupling reactions.
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