Journal
ORGANIC LETTERS
Volume 17, Issue 11, Pages 2784-2787Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.5b01198
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Funding
- National Basic Research Program of China [2015CB856600]
- NSFC [21422206, 21272206]
- Fundamental Research Funds for the Central Universities
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A copper-catalyzed direct sulfonylation of C(sp(2))-H bonds with sodium sulfinates using a removable directing group is described. This reaction tolerates a wide range of functional groups, providing an efficient protocol for the synthesis of diverse aryl sulfones. Moreover, a series of 2,6-disubstituted benzamides could be synthesized via sequential C-H functionalization.
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