Journal
ORGANIC LETTERS
Volume 17, Issue 10, Pages 2482-2485Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.5b00990
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Funding
- NSFC [21272205, 21472165]
- NBRPC [2011CB936003]
- Program for Zhejiang Leading Team of ST Innovation [2011R50007]
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The efficient nickel-catalyzed direct amination of arenes with simple alkylamines has been achieved with the assistance of a bidentate directing group through sp(2) C-H bond functionalization. Preliminary mechanistic investigations indicate that the reaction probably proceeds through a Ni-I/Ni-III catalytic pathway.
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