Journal
ORGANIC LETTERS
Volume 17, Issue 21, Pages 5228-5231Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.5b02572
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Funding
- NSFC [21373003, 21273068, J1210040]
- Fundamental Research Funds for the Central Universities
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Nickel-catalyzed heteroarylation of the inactive methyl C(sp(3))-H bond of aliphatic amide with heteroarenes is described. The method takes advantage of chelation assistance by an 8-aminoquinolinyl moiety. The synthetic reaction has good tolerance toward functional groups, and it can be used in the construction of various hinds of alkyl-substituted heteroarenes.
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