Journal
ORGANIC LETTERS
Volume 17, Issue 19, Pages 4782-4785Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.5b02345
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Funding
- Scottish Funding Council
- EPSRC [EP/K503903/1]
- SINAPSE
- Engineering and Physical Sciences Research Council [EP/K503903/1] Funding Source: researchfish
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An iron(III)-catalyzed method for the rapid and highly regioselective iodination of arenes has been developed. Use of the powerful Lewis acid, iron(III) triflimide, generated in situ from iron(III) chloride and a readily available triflimide-based ionic liquid allowed activation of N-iodosuccinimide (NIS) and efficient iodination under mild conditions of a wide range of substrates including biologically active compounds and molecular imaging agents.
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