Journal
ORGANIC LETTERS
Volume 17, Issue 11, Pages 2598-2601Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.5b00878
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Funding
- Council of Scientific and Industrial Research (CSIR), India [RP02948]
- CSIR
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An unprecedented Pd(OAc)(2)-catalyzed decarboxylative alkylation of unactivated arenes, with aliphatic carboxylic acids as inexpensive alkyl Sources, is reported. alkylation, controlled by the directing group, is regioselective, shows high functional group tolerance, and prorvides mild access to alkylated indolines, 2-phenylpyridines, and azobenzenes under solvent-free conditions in moderate to high yields.
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