Journal
ORGANIC LETTERS
Volume 17, Issue 19, Pages 4926-4929Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.5b02458
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Funding
- National Natural Science Foundation of China [21372212]
- National Basic Research Program of China [2015CB856600]
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The C-H arylation of (benzo)oxazoles or (benzo)thiazoles with aryltrimethylammonium triflates was carried out via Pd-catalyzed C-H/C-N cleavage. Oxazoles, thiazoles, benzoxazole, and benzothiazole were arylated using activated and deactivated aryltrimethylamrnonium triflates to give 2-aryl(benzo)oxazoles or 2-aryl(benzo)thiazoles in reasonable to excellent yields.
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