Journal
ORGANIC LETTERS
Volume 17, Issue 8, Pages 1834-1837Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.5b00213
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- Sun Yat-Sen University
- One Thousand Youth Talents Program of China
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An efficient route to prepare 3-amino allylic alcohols in excellent regio- and stereoselectivity in the presence of bases by orangoselenium catalysis has been developed. In the absence of bases alpha,beta-unsaturated aldehydes were formed in up to 97% yield. Control experiments reveal that the hydroxy group is crucial for the direct amination.
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