Journal
ORGANIC LETTERS
Volume 17, Issue 8, Pages 1830-1833Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.5b00625
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Funding
- Basic Science Research Program through the National Research Foundation of Korea (NRF) - Ministry of Education, Science and Technology [2013R1A1A1009618]
- National Research Foundation of Korea [2013R1A1A1009618] Funding Source: Korea Institute of Science & Technology Information (KISTI), National Science & Technology Information Service (NTIS)
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C-N-coupled heterobiaryls were synthesized by sequential N-H functionalization reactions: stereoselective rhodium-catalyzed N-H insertion, followed by regioselective palladium-catalyzed C-H amination. Because of the good substrate scope and excellent selectivity, the developed method presents a novel approach for the synthesis of heterobiaryls, which are potent antibiotics.
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