Journal
ORGANIC LETTERS
Volume 18, Issue 2, Pages 212-215Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.5b03328
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Funding
- National Research Foundation of Korea [NRF-2014R1A2A1A11050028, NRF-2014S1A2A2028156, NRF-2015M1A8A1048891]
- Institute for Basic Science - Korean Government [IBS-R006-D1]
- NRF Fostering Core Leaders of the Future Basic Science Program
- National Research Foundation of Korea [2015M1A8A1048891, 2014S1A2A2028156] Funding Source: Korea Institute of Science & Technology Information (KISTI), National Science & Technology Information Service (NTIS)
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An unprecedented protocol for urea synthesis directly from methanol and amine was accomplished. The reaction is highly atom-economical, producing hydrogen as the sole byproduct. Commercially available ruthenium pincer complexes were used as catalysts. In addition, no additive, such as a base, oxidant, or hydrogen acceptor, was required. Furthermore, unsymmetrical urea derivatives were successfully obtained via a one-pot, two-step reaction
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