Journal
ORGANIC LETTERS
Volume 17, Issue 10, Pages 2342-2345Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.5b00829
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Funding
- NSF of China [21372016, 21402002]
- 863 Program [2013AA092903]
- 973 Program [2012CB722602]
- NSFC-Shandong Joint Fund for Marine Science Research Centers [U1406402]
- Shenzhen Basic Research Program [JCYJ20130329180217059, ZDSYS20140509094114168]
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A highly enantio- and diastereoselective synthesis of the left-wing fragment of 11-epi-azadirachtin I characterized with the pairwise Use of palladium- and gold-catalyzed cascade reactions is presented. By enlisting a sequence of stereocontrolled transformations, our 21-step route established the stereocenters of the left-wing fragment from one chiral starting material, (-)-carvone, which would significantly facilitate the synthetic studies of the azadirachtin-type limonoids.
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