Journal
ORGANIC LETTERS
Volume 17, Issue 23, Pages 5725-5727Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.5b02809
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Funding
- National Natural Science Foundation of China (NSFC) [21372129, 81370086]
- Program for New Century Excellent Talents in University
- Hundred Young Academic Leaders Program of Nankai University
- China Postdoctoral Science Foundation [2015M571261]
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The absolute configurations of the three unknown chiral centers in vinylamycin were predicted according to the structural comparison with microtermolide A and rakicidin A, and then total syntheses of vinylamycin were applied to determine the three unknown chiral centers as 14R, 15R, and 16S.
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