4.8 Article

Synthesis of Cinnolin-3(2H)-one Derivatives from Rh-Catalyzed Reaction of Azobenzenes with Diazotized Meldrum's Acid

Journal

ORGANIC LETTERS
Volume 17, Issue 10, Pages 2518-2521

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.5b01052

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Funding

  1. National Research Foundation of Korea (NRF) - Korea government (MSIP) [2014001403]
  2. National Research Foundation of Korea [2011-0018355] Funding Source: Korea Institute of Science & Technology Information (KISTI), National Science & Technology Information Service (NTIS)

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A synthetic method of a wide range of cinnolin-3(2H)-one derivatives is developed from the reaction of symmetrical as well as unsymmetrical azobenzenes with diazotized Meldrum's acid via Rh-catalyzed C-H alkylation followed by cyclization.

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