Journal
ORGANIC LETTERS
Volume 17, Issue 4, Pages 986-989Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.5b00083
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Funding
- National Natural Science Foundation of China [21272021, 21472011]
- National Key Technology RD Program [2011BAD23B01]
- US National Science Foundation [OISE-0968399]
- Division Of Chemistry
- Direct For Mathematical & Physical Scien [1240194] Funding Source: National Science Foundation
- Office Of The Director
- Office Of Internatl Science &Engineering [0968399] Funding Source: National Science Foundation
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Efficient electrocatalytic aziridination of alkenes has been achieved for the first time. A structurally broad range of aziridines was easily accessed using an undivided cell operated at constant current and mediated by a catalytic quantity of n-Bu4NI. The electrocatalytic reaction also proceeded in the absence of additional conducting salt. The aziridination is proposed to follow a radical mechanism.
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