4.8 Article

Synthesis and Electroluminescence of Novel Pyrene-Fused Chromophores

Journal

ORGANIC LETTERS
Volume 17, Issue 16, Pages 3960-3963

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.5b01793

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Funding

  1. Fundamental R&D Program for Core Technology of Materials - Ministry of Trade, Industry and Energy, Republic of Korea [10050215]
  2. Korea Evaluation Institute of Industrial Technology (KEIT) [10050215] Funding Source: Korea Institute of Science & Technology Information (KISTI), National Science & Technology Information Service (NTIS)

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Using 4,9-dibromopyrene as a key intermediate, two new fused-core compounds, TP-PFF and TP-PFC-TP, were synthesized. These compounds not only exhibited excellent thermal stability but also yielded superior electroluminescence (EL) devices with a lower turn-on voltage, over 50% greater efficiency, and over 3 times longer lifetime than did a similar compound lacking a fused core. This new core-forming method can be applied in various applications with many different core groups.

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