Journal
ORGANIC LETTERS
Volume 17, Issue 24, Pages 5994-5997Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.5b02940
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Funding
- National Basic Research Program of China (973) [2015CB856603]
- National Natural Science Foundation of China [20472096, 21372241, 21361140350, 20672127, 21421091, 21372250, 21121062, 21302203, 20732008, 21572052]
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Copper(I)-catalyzed intramolecular trifluoromethylation of methylenecyclopropanes has been developed to produce a variety of CF3-substituted dihydronaphthalenes in moderate to good yields, relying on the construction of C(sp(2))-CF3 bonds under mild conditions. The reactions proceed through a radical process under copper(I) catalysis with a good compatibility for the functional group.
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