4.8 Article

Synthesis of Spiro Ketals, Orthoesters, and Orthocarbonates by CpRu-Catalyzed Decomposition of α-Diazo-β-ketoesters

Journal

ORGANIC LETTERS
Volume 18, Issue 2, Pages 240-243

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.5b03380

Keywords

-

Funding

  1. University of Geneva
  2. Swiss National Science Foundation

Ask authors/readers for more resources

Reactions of alpha-diazo-beta-ketoesters with cyclic ketones, lactones, and carbonates are reported. Thanks to the combined use of salt [CpRu(CH3CN)(3)][BArF] and 1,10-phenanthroline as catalyst for the diazo decomposition, effective and practical syntheses of spiro bicyclic ketals, orthoesters, and orthocarbonates are afforded.

Authors

I am an author on this paper
Click your name to claim this paper and add it to your profile.

Reviews

Primary Rating

4.8
Not enough ratings

Secondary Ratings

Novelty
-
Significance
-
Scientific rigor
-
Rate this paper

Recommended

No Data Available
No Data Available