Journal
ORGANIC LETTERS
Volume 17, Issue 7, Pages 1716-1719Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.5b00494
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Funding
- German Research Foundation (DFG)
- Fonds der Chemischen Industrie
- Studienstiftung des deutschen Volkes
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Palladium-catalyzed activation of carbon-sulfur bonds allows aryne insertion into aryl thiocyanates to generate new C-SAr and C-CN bonds in one step. The readily available starting materials make this method efficient in generating a variety of 1,2-thiobenzonitriles. By choosing an oxygen atmosphere the yields are increased and side reactions are minimized.
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