Journal
ORGANIC LETTERS
Volume 17, Issue 7, Pages 1728-1731Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.5b00509
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- University of Bologna
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The atroposelective desymmetrization of N-arylmaleimides was realized by means of a primary amine catalyzed Diels-Alder reaction of enones. The chiral axis as new element of chirality is generated under the remote control of the catalyst that selectively drives the formal Diels-Alder reaction through an exclusive stereochemical outcome.
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