Journal
ORGANIC LETTERS
Volume 17, Issue 7, Pages 1664-1667Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.5b00378
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Funding
- JST
- Ministry of Education, Culture, Sports, Science, and Technology, Japan [23245031]
- Grants-in-Aid for Scientific Research [23245031] Funding Source: KAKEN
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Palladium-containing macrocycle catalysts (PdMCs) with different ring sizes ranging from 24 to 30 members were synthesized. The intramolecular hydroamination of an allylurethane (AU) catalyzed by PdMCs proceeded efficiently to afford the corresponding oxazolidinone (OZ) in 95% isolated yield. The dependence of the hydroamination of AU to OZ on the cavity size indicated that the reaction rate was clearly controlled by both substrate uptake and product release steps.
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