Journal
ORGANIC LETTERS
Volume 17, Issue 5, Pages 1098-1101Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol5036326
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Funding
- Natural Science Foundation of China [21172120, 21472093]
- Tianjin Municipal Science and Technology Commission [14JCYBJC20600]
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A S-O bond insertion reaction of sulfoxides with arynes is reported. This reaction represents a rare instance of semipolar single bond insertion in aryne chemistry. The study of mechanism indicates that a sulfur ylide triggered by aryne is the key intermediate, which further transfers its methylene group to carbonyl compounds to give epoxides and thioethers through a sequential process.
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