Journal
ORGANIC LETTERS
Volume 17, Issue 3, Pages 616-619Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ol503630z
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- Suhara Memorial Foundation
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Alternative one-pot synthesis of 3-(trifluoromethyl)-3-phenyldiazirine derivatives from corresponding tosyloximes is developed. The deprotonation of intermediate diaziridine by NH2- is a new approach for construction of diazirine. Moreover, a novel synthesis of optically pure (trifluoromethyl)diazirinylphenylalanine derivatives was attempted involving these methods.
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