Journal
ORGANIC LETTERS
Volume 17, Issue 19, Pages 4838-4841Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.5b02403
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Funding
- Natural Sciences and Engineering Research Council of Canada (NSERC)
- University of Toronto
- Alphora Inc.
- Canada Council for the Arts
- NSERC
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The first Pd-catalyzed dearomative indole bisfunctionalization via a diastereoselective arylcyanation is reported. This method facilitates the formation of diverse indoline scaffolds bearing congested stereocenters with high levels of diastereoselectivity. This also represents the first example of a cyanation mechanism involving a 2 benzylic Pd(II) intermediate.
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