Journal
ORGANIC LETTERS
Volume 17, Issue 19, Pages 4730-4733Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.5b02221
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Funding
- Ministerio de Economia y Competitividad (MINECO) [AGL2013-42238-R]
- Consejena de Economia Innovacion y Ciencia, Junta de Andalucia [DP12-TEP-725]
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Four novel compounds (1-4) with an unprecedented skeleton that combines a sesquiterpene lactone and a-kaurane diterpene acid were isolated from Helianthus annuus L. var. Arianna extract, which was obtained under supercritical conditions. The structures of 1 4 were elucidated by NMR and MS analyses. The biosynthetic routes involve sesquiterpene lactones and kauranic acid, both of which were previously isolated from this species.
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