Journal
ORGANIC LETTERS
Volume 17, Issue 15, Pages 3682-3685Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.5b01612
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Funding
- National Natural Science Foundation of China [21272050, 21472033, 21325208, 21361140372]
- Program for New Century Excellent Talents in University of the Chinese Ministry of Education [NCET-11-0627]
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The cross-coupling reaction of allyl boron ester with 1 degrees/2 degrees/3 degrees-halogenated alkanes in the presence of copper has been developed for the first time, which provides a mild and efficient method for the construction of saturated C(sp(3))C(sp(3)) bonds. This protocol shows excellent compatibility with the nonactivated primary, secondary, and even tertiary halogenated alkanes under mild conditions.
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