Journal
ORGANIC LETTERS
Volume 17, Issue 12, Pages 3106-3109Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.5b01380
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Funding
- National Basic Research Program of China (973 program) [2011CB808600]
- National Natural Science Foundation of China [21222207]
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A highly stereoselective metal-free hydrogenation of vicinal diimines has been successfully realized for the first time using 5-10 mol % of Piers borane as a catalyst under mild conditions, and a variety of cis-1,2-diamines were obtained in 92-99% yields. The current work provides a novel and efficient approach for the synthesis of vicinal diamines.
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