Journal
ORGANIC LETTERS
Volume 17, Issue 18, Pages 4506-4509Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.5b02195
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Funding
- Swedish Research Council
- Lars Hierta Memorial Foundation
- Carl Trygger Foundation
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A highly selective Lewis acid catalyzed annulation of three-membered heterocycles with nitrones has been developed. Oxiranes, aziridines, and thiiranes were used as substrates for the synthesis of various six-membered heterocycles using Al or In catalysts. This catalytic protocol demonstrates a broad substrate scope and provides access to new structural motifs in high yields and in excellent selectivity under mild reaction conditions.
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