Journal
ORGANIC LETTERS
Volume 17, Issue 19, Pages 4754-4757Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.5b02285
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Funding
- Swedish Research Council (VR)
- Knut och Alice Wallenbergs Foundation
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Copper-catalyzed cross-coupling of substituted allylboronic acids with alpha-diazoketones was studied. This allylation reaction is highly regioselective, providing the branched allylic product. The process involves creation of a new C(sp(3))-C(sp(3)) bond by retaining the keto functional group of the alpha-diazoketone precursor.
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