Journal
ORGANIC LETTERS
Volume 17, Issue 22, Pages 5722-5724Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.5b02926
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Funding
- National Natural Science Foundation [21272218]
- Specialized Research Fund for the Doctoral Program of Higher Education [20134101110004]
- Henan Science and Technology Department [144300510011]
- Zhengzhou Science and Technology Department [131PYSGZ204]
- Zhengzhou University of China
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Under Pd(II)/CuI cocatalysis, o-diarylphosphinophenylalkynes cyclize in boiling toluene via CP bond cleavage and arylphosphination of the C=C bond. This protocol provides an unprecedented atom- and step-efficient access to optoelectronically and biologically interesting benzophospholes.
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