Journal
ORGANIC LETTERS
Volume 17, Issue 14, Pages 3580-3583Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.5b01677
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Funding
- National Basic Research Program of China [973-2015CB856600]
- National Nature Science Foundation of China [21225210, 21421091, 21472219]
- Science Technology Commission of the Shanghai Municipality [12ZR1453400]
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A mild and efficient method for copper-catalyzed trifluoromethylazidation and trifluoromethylthiocyanation of allenes was explored. A series of CF3-containing allyl azides and thiocyanates were obtained with high yields and good stereoselectivities, which can be used for further transformation to some valuable compounds.
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