Journal
ORGANIC LETTERS
Volume 17, Issue 5, Pages 1292-1295Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.5b00282
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Funding
- MEXT
- JSPS
- Grants-in-Aid for Scientific Research [26248031] Funding Source: KAKEN
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beta- or gamma-Site-selective C-H alkylation of aliphatic nitriles has been achieved using a decatungstate salt as the photocatalyst. The observed site selectivity was justified by a radical polar effect in transition states for hydrogen abstraction.
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