4.8 Article

Palladium N-Heterocyclic Carbene Precatalyst Site Isolated in the Core of a Star Polymer

Journal

ORGANIC LETTERS
Volume 17, Issue 19, Pages 4826-4829

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.5b02388

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Funding

  1. King Abdullah University of Science and Technology

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An approach for supporting a Pd-NHC complex on a soluble star polymer with nanoscale dimensions is described. The resulting star polymer catalyst exhibits excellent activity in cross-coupling reactions, is stable in air and moisture, and is easily recoverable and recyclable. These properties are distinct and unattainable with the small-molecule version of the same catalyst.

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