Journal
ORGANIC LETTERS
Volume 18, Issue 2, Pages 204-207Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.5b03292
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- Deutsche Forschungsgemeinschaft
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An efficient synthetic protocol for the stereoselective synthesis of cyclomarin A is reported. Key steps in the syntheses of the building blocks are an asymmetric chelate-enolate Claisen rearrangement, an asymmetric hydrogenation, and highly diastereoselective additions of organozinc and -titanium reagents.
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