Journal
ORGANIC & BIOMOLECULAR CHEMISTRY
Volume 13, Issue 31, Pages 8425-8428Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c5ob01243k
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Funding
- National Natural Science Foundation of China (NSFC) [21402081, 21362043, 21302162]
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A combination of iridium/copper associated with (R)-Difluorphos catalyst for the asymmetric ring opening reaction of azabenzonorbornadienes with amines was developed, which afforded chiral trans-vicinal diamines in 80-97% yields with 93-95% enantioselectivities.
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