4.6 Article

Manganese triacetate as an efficient catalyst for bisperoxidation of styrenes

Journal

ORGANIC & BIOMOLECULAR CHEMISTRY
Volume 13, Issue 5, Pages 1439-1445

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c4ob01823k

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Funding

  1. Russian Science Foundation [14-23-00150]
  2. Russian Science Foundation [14-23-00150] Funding Source: Russian Science Foundation

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A method was developed for the bisperoxidation of styrenes with tert- butyl hydroperoxide in the presence of a catalytic amount of manganese(III) acetate. It was shown that compounds of manganese in oxidation states 2, 4, and 7 also catalyze this reaction. The target [1,2-bis(tert-butylperoxy)ethyl] arenes were synthesized in yields from 46 to 75%.

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