Journal
ORGANIC & BIOMOLECULAR CHEMISTRY
Volume 13, Issue 20, Pages 5710-5715Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c5ob00277j
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Funding
- National Science Foundation of China [21202093, 21472112]
- Program for New Century Excellent Talents in University [NCET-13-0346]
- Shandong Science Fund for Distinguished Young Scholars [JQ201404]
- Young Scientist Foundation Grant of Shandong Province [BS2013YY001]
- Fundamental Research Funds of Shandong University [2014JC005]
- Key Laboratory for the Chemistry and Molecular Engineering of Medicinal Resources (Guangxi Normal University), Ministry of Education of China [CHEMR2014-B11]
- Program for Changjiang Scholars and Innovative Research Team in University [IRT13028]
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An effective indium-catalyzed oxidative cross-dehydrogenative coupling of electronically varied chromenes with 1,3-dicarbonyl compounds and aryl rings has been established. Both the C-H alkylation and arylation proceed smoothly at room temperature to afford diverse a-substituted chromene compounds in up to 91% yields. Besides these two types of C-H components, simple ketones like cyclohexanones also prove to be well tolerated.
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