Journal
ORGANIC & BIOMOLECULAR CHEMISTRY
Volume 13, Issue 17, Pages 4841-4845Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c5ob00235d
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Funding
- DST, Govt. of India [SR/S2/RJN-97/2012]
- NIPER, Kolkata
- CSIR
- UGC
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Heck arylation with allylic alcohol is extremely challenging due to chemo-, regio-, and stereoselective scrambling. Here we report a mild protocol for the alcohol selective beta- and alpha-arylation of allylic and cinnamyl alcohols respectively with aryldiazonium salts. The steric and electronic parameters of the alkene play a prominent role in the regioselectivity.
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