Journal
ORGANIC & BIOMOLECULAR CHEMISTRY
Volume 13, Issue 47, Pages 11432-11437Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c5ob01258a
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An efficient copper-catalyzed cross-coupling reaction of biguanide hydrochloride derivatives with both aryl iodides and bromides under mild conditions has been developed. The reaction occurred in good yields and tolerated aryl halides containing functionalities such as nitriles, sulfonamides, ethers, and halogens. Alkyl and cyclic substituted biguanidines were also well tolerated.
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