Journal
ORGANIC & BIOMOLECULAR CHEMISTRY
Volume 13, Issue 17, Pages 4855-4858Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c5ob00523j
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Funding
- National Natural Science Foundation of P. R. China [21372202, 21402175]
- New Century Excellent Talents in University [NCET-12-1086]
- Zhejiang Natural Science Fund for Distinguished Young Scholars [R14B020005]
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A novel method for the C-C bond cleavage of cyclopropanes was developed by gold-catalyzed cycloisomerization of 2-(1-alkynyl-cyclopropyl)pyridine with nucleophiles, which provides efficient access to structurally diverse indolizines under mild conditions. A series of N-, C- and O-based nucleophiles were involved in this reaction to afford the corresponding indolizines in modest to excellent yields.
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