Journal
ORGANIC & BIOMOLECULAR CHEMISTRY
Volume 13, Issue 25, Pages 6891-6905Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c5ob00697j
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Funding
- Kerala State Council for Science, Technology and Environment (KSCSTE), Trivandrum [341/2013/KSCSTE]
- University Grants Commission (UGC), New Delhi
- KSCSTE, Trivandrum
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The classical heterocoupling of a 1-haloalkyne with a terminal alkyne catalyzed by copper salts in the presence of a base for the synthesis of unsymmetrical diynes is termed the Cadiot-Chodkiewicz coupling reaction. The diynes are of great importance due to their biological, optical and electronic properties. A number of modifications have been developed recently to improve the efficiency of Cadiot-Chodkiewicz coupling reactions in terms of selectivity and yield. This is the first review on the Cadiot-Chodkiewicz cross-coupling reaction which highlights the modern approaches and protocols developed for the synthesis and applications of unsymmetrical 1,3-diynes.
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