Journal
ORGANIC & BIOMOLECULAR CHEMISTRY
Volume 13, Issue 7, Pages 2026-2033Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c4ob02077d
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Funding
- COST Action [CM1005]
- Ministerio de Ciencia e Innovacion of Spain [CTQ2012-31335]
- Fundacao para a Ciencia e Tecnologia of Portugal [PTDC/QUI-QUI/112597/2009, PEst-C/EQB/LA0006/2011]
- Academy of Finland [263256, 265328]
- FCT [SFRH/BPD/69210/2010]
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A phosphine-gold(I)-alkynyl-coumarin complex, [Au{7-(prop-2-ine-1-yloxy)-1-benzopyran-2-one}-(DAPTA)] (1), was synthesized and the formation of long luminescent fibers in solution was characterized via fluorescence microscopy and dynamic light scattering. The fibers presented strong blue and green luminescence, suggesting that the gold(I) in the complex increased intersystem crossing due to the heavy atom effect, resulting in a significant increase in triplet emission. The X-ray structure of the fibers indicates that both aurophilic, pi-pi interactions and hydrogen bonding contribute to their formation in aqueous solvents.
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